Overnight they sailed up the St Lawrence river to the city, where they are due to visit a youth project and attend a military ceremony.
In Montreal about 60 protesters heckled the couple outside a hospital.
There was also a much larger number of well-wishers.
Canadian barbecueThe Duke and Duchess' agenda for Sunday also involves morning prayers with the crew of the Canadian frigate on which they are travelling, HMCS Montreal, on the ship's helicopter deck.
The military ceremony in Quebec City will honour the Royal 22nd Regiment of Canada, as well as a Freedom of the City Ceremony, at Quebec City Hall.
The couple will also attend a community event, including barbecues and stalls, before a short flight to Prince Edward Island.
Prince Edward Island is the most easterly point of the tour, and is known as the home of Anne of Green Gables - a fictional character said to be a favourite of the duchess.
Continue reading the main story 30 June: Arrival in Ottawa1 July: Canada Day celebrations in Ottawa2 July: Visit to a Montreal cookery school 3 July: Freedom of the city ceremony in Quebec City4 July: William takes part in Sea King helicopter training session on Prince Edward Island5 July: Visit to Yellowknife, Northwest Territories7 July: Arrival in Calgary8 July: Attend Calgary Stampede. Leave for USThe official welcome to Prince Edward Island is on Monday, and the Canadian government expects their visit may be a focal point for many well-wishers from across the Maritimes provinces, Clarence House said earlier.On Monday, still on Prince Edward Island, Prince William will take part in a Sea King helicopter training session.
A dragon boat race is scheduled for later, with the husband and wife steering opposing teams.
Their first overseas tour has involved a tree-planting ceremony in the grounds of Government House, in Ottawa; a Montreal children's hospital visit; and a citizenship ceremony for 25 new Canadians who had come from 12 different countries.
They were also guests of honour for celebrations for Canada Day, when about 100,000 people joined events on Parliament Hill as part of a national holiday to mark the country's 144th birthday.
The protesters outside the hospital the couple visited in Montreal shouted "down with the monarchy" and "We will never bend, Willy go home!"
They also chanted "French Quebec!" and "Parasite go home!"
The couple are visiting seven Canadian cities in eight days in their first official overseas tour.
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